تفاعل #1771991

ord-696188d0a22a43afa651f35351c4c027

معادلة التفاعل

CC1(C)C[C@@H](C(=O)O)N(C(=O)OC(C)(C)C)C1
Boc-Pro(4,4-diMe)-OH
O=S(Cl)Cl
thionylchloride
CO
methanol
COC(=O)[C@@H]1CC(C)(C)CN1.Cl
4,4-Dimethylproline Methylester Hydrochloride Salt

الكواشف

لا شيء

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    تركيزThe reaction mixture was concentrated to an amorphous solid (377 mg, 95%)

الإجراء التجريبي

To a solution of Boc-Pro(4,4-diMe)-OH (0.5 g, 2.06 mmol) in anhydrous methanol (8 ml) was added dropwise thionylchloride (448 g, 6.18 mmol) and the reaction was stirred for six hours at room temperature. The reaction mixture was concentrated to an amorphous solid (377 mg, 95%).

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: USRE043298E1uspto-grants-2012_04