تفاعل #1726654

ord-65eed43cf6744f63b32103934bf27a48

معادلة التفاعل

CCCCCCCCCCCCCCCC(=O)OC
methyl palmitate
CCCCCCCCCCCCCCCC(=O)OC
Methyl palmitate
C=CCCCCCCCCCCCC
1-tetradecene

الكواشف

لا شيء

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

الإجراء التجريبي

Irradiation of methyl palmitate. Methyl palmitate was dissolved in a small amount of hexane and irradiated in a quartz container (UV cuvette) at 253.7 nm in the Rayonet reactor. After 7 hours a small amount of 1-tetradecene was formed. After 24 hours a larger amount of 1-tetradecene and a corresponding isomer (to be identified but likely 2-tetradecene (CH3CH═CHCH2(CH2)9CH3) was obtained.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US08110074B1uspto-grants-2012_02