تفاعل #171129

ord-01b081e27a914390b17b8bb8f541974c

معادلة التفاعل

C=C1CCOC1=O
α-methylene-γ-butyrolactone
C=CC(=O)OCCCC
n-butyl acrylate
C=CC(=O)OCCCC
n-butyl acrylate
C=C1CCOC1=O.C=CC(=O)O.C=CC(=O)OCCCC
α-methylene-γ-butyrolactone n-butyl acrylate acrylic acid

الكواشف

لا شيء

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىyielding a polymer with a glass transition temperature of 145° C

الإجراء التجريبي

Similar to Example 51, with the following exception: 3.390 g (3.46×10−2 mol) α-methylene-γ-butyrolactone and 1.075 g (8.39×10−3 mol) n-butyl acrylate were used in the monomer mixture, yielding a polymer with a glass transition temperature of 145° C. Comparison to the Fox equation suggests the statistical copolymer contains approximately 11% n-butyl acrylate repeat units.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US08846817B2uspto-grants-2014_09