تفاعل #1687677

ord-e9c2f5d9ccaa46e5b74c358a16261713

معادلة التفاعل

C=Cc1ccc(OC(C)(C)C)cc1
p-tert-butoxystyrene
C=Cc1ccccc1
styrene
C=Cc1ccc(OC(C)(C)C)cc1.C=Cc1ccccc1
p-tert-butoxystyrene styrene

الكواشف

لا شيء

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىmaterials, polymerization reaction

الإجراء التجريبي

Using 81.1 g (0.46 mol) of p-tert-butoxystyrene and 4.6 g (0.04 mol) of styrene as starting materials, polymerization reaction and after-treatments were carried out according to the procedure of (1) of Preparation Example 1 to give 77.1 g of poly(p-tert-butoxystyrene/styrene) as white powdery crystal. P-tert-butoxystyrene unit/styrene unit molar ratio in the polymer≈92:8 (1H NMR). Mw≈20,000 (GPC with polystyrene calibration).

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US05976759uspto-grants-1999_11