تفاعل #1687654

ord-6e2e1cb222ad4fc58aeec33ba35c2003

معادلة التفاعل

O=S=O
sulfur dioxide
[Na+].[OH-]
caustic soda
O=S([O-])[O-].[Na+].[Na+]
sodium sulfite
O=S([O-])S(=O)(=O)[O-].[Na+].[Na+]
sodium metabisulfite

الكواشف

لا شيء

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    workup.ADDITIONthereof is added

الإجراء التجريبي

Sulfur dioxide is introduced into a solution of sodium sulfite and sodium bisulfite to form sodium bisulfite in a solution having dissolved sulfur dioxide present with a pH between 3.5 and 4.2. The solution is drawn to a cooling crystallizer where an alkali such as soda ash, caustic soda, sodium sulfite, and mixtures thereof is added to produce additional sodium metabisulfite that increases the yield of sodium metabisulfite crystallizing per pass. The mother liquor is recycled.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US05976485uspto-grants-1999_11