تفاعل #165941

ord-ceab3169e0434567a1d9d218c6b97114

معادلة التفاعل

[N-]=[N+]=NCC(COS(=O)(=O)[O-])([N+](=O)[O-])[N+](=O)[O-].[Na+]
sodium 3-azido-2,2-dinitropropyl sulfate
O=S(=O)(O)O
sulfuric acid
→
[N-]=[N+]=NCC(CO)([N+](=O)[O-])[N+](=O)[O-]
3-azido-2,2-dinitropropanol

المتفاعلات

—
cyclic sulfate
[N-]=[N+]=NCC(COS(=O)(=O)[O-])([N+](=O)[O-])[N+](=O)[O-].[Na+]
sodium 3-azido-2,2-dinitropropyl sulfate
O=S(=O)(O)O
sulfuric acid

الكواشف

لا شيء

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

الإجراء التجريبي

Scheme 3 illustrates the conversion of 2,2-dinitro 1,3-propanediol cyclic sulfate into 3-azido 2,2-dinitropropanol. First, 2,2-dinitro 1,3-propanediol cyclic sulfate is reacted with sodium azide and dimethylformamide (“DMF”) to open the cyclic sulfate and form sodium 3-azido-2,2-dinitropropyl sulfate. After the cyclic sulfate is opened, the sodium 3-azido-2,2-dinitropropyl sulfate is reacted with 20% sulfuric acid to form 3-azido-2,2-dinitropropanol.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US08841468B2uspto-grants-2014_09