تفاعل #1470425

معادلة التفاعل

1-oxyl-2,2,6,6-tetramethyl-4-glycidyloxypiperidine

diethanolamine

→

title compound

المردود 29.9%

1-Oxyl-2,2,6,6-tetramethyl-4-{2-hydroxy-3-[di(2-hydroxyethyl)amino]propoxy}piperidine

المردود 29.9%

المذيبات

water

ظروف التفاعل

المعالجة

1. 1
   استخلاصThe solution is then extracted with methylene chloride
2. 2
   استخلاصThe methylene chloride extract
3. 3
   تجفيفis dried over anhydrous magnesium sulfate
4. 4
   ترشيحfilter
5. 5
   تركيزconcentrated
6. 6
   أخرىThe crude reaction product
7. 7
   أخرىis purified by column chromatography

الإجراء التجريبي

A solution of 2.28 g (0.01 mol) of 1-oxyl-2,2,6,6-tetramethyl-4-glycidyloxypiperidine and 1.05 g (0.01 mol) of diethanolamine in 25 mL of water is stirred at ambient temperature for 16 hours. The solution is then extracted with methylene chloride. The methylene chloride extract is dried over anhydrous magnesium sulfate, filter and concentrated. The crude reaction product is purified by column chromatography to afford 1.0 g of the title compound as a red oil.

المصدر