تفاعل #1458415
ord-1bc0273f6d9e4898b5a2d888224182f6
معادلة التفاعل
p-chlorophenyl acetate
isopropenyl acetate
→
(R)-1-phenylethyl acetate
المردود 95.0%
الكواشف
لا شيء
ظروف التفاعل
الظروف التفصيلية
See reaction.notes.procedure_details.
المعالجة
- 1أخرىused in Example 1 over a reaction period of 42 hours
الإجراء التجريبي
The procedure of Example 1 was repeated except that 3 molar equivalents of p-chlorophenyl acetate (a conventional acylating agent) was used in place of isopropenyl acetate in the presence of three times the amount of the enzyme catalyst used in Example 1 over a reaction period of 42 hours, to obtain (R)-1-phenylethyl acetate having an optical purity of higher than 99%, at a yield of 95%.