تفاعل #1076742

ord-b80a1c54b00442ef9e8d5fa0d4abfda0

معادلة التفاعل

O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Ca+2]
calcium nitrate salt
O.O.O=P([O-])([O-])[O-].[Ca+2].[Ca+2]
dicalcium phosphate dihydrate
C1=CC2C(C1)[C@@H]1C=C[C@H]2C1
DCPD
O=P([O-])([O-])OP(=O)([O-])[O-].[Ca+2].[Ca+2]
calcium pyrophosphate
C1=CC2C(C1)[C@@H]1C=C[C@H]2C1
DCPD
O=P([O-])([O-])[O-].O=P([O-])([O-])[O-].[Ca+2].[Ca+2].[Ca+2]
Calcium Phosphate

ظروف التفاعل

درجة الحرارة
500°CELSIUS
الظروف التفصيلية
See reaction.notes.procedure_details.

المعالجة

  1. 1
    أخرىas precipitated material (no agitation
  2. 2
    درجة الحرارةWarming of the sample to >25° C.
  3. 3
    أخرىan exothermic reaction
  4. 4
    أخرىresulting in the formation of a white, pasty solid
  5. 5
    درجة الحرارةHeat treatment and X-ray diffraction of this solid

الإجراء التجريبي

Example 1 was repeated with the addition of 10.00 g dicalcium phosphate dihydrate, DCPD, CaHPO4.2H2O (Aldrich Chemical Co., Inc. #30,765-3, CAS #7789-77-7) to the homogeneous solution following endothermic dissolution of the calcium nitrate salt. The DCPD was present both as suspended solids and as precipitated material (no agitation used). Warming of the sample to >25° C. initiated an exothermic reaction as described in Example 1, resulting in the formation of a white, pasty solid. Heat treatment and X-ray diffraction of this solid were conducted as described in Example 1. Following heat treatment in air at 500° C. for 1 hour, XRD indicated the solid to be composed of whitlockite as the primary phase along with calcium pyrophosphate (Ca2P2O7) as the secondary phase.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US06458162B1uspto-grants-2002_10