تفاعل #10227

ord-bf0fdec98e874af7be6a18c9a6110a97

معادلة التفاعل

CC(C)(C)OC(=O)CC(=O)C[C@H](O)COC(=O)c1ccccc1
(5S)-6-benzoyloxy-5-hydroxy-3-oxohexanoic tert-butyl ester
O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO
glucose
CC(C)(C)OC(=O)C[C@H](O)C[C@H](O)COC(=O)c1ccccc1
(3R,5S)-6-benzoyloxy-3,5-dihydroxyhexanoic tert-butyl ester

الكواشف

لا شيء

المذيبات

ظروف التفاعل

الظروف التفصيلية
See reaction.notes.procedure_details.

الإجراء التجريبي

Using 5 ml of Medium C described hereinbefore, the microorganisms indicated in Table 4 were cultured in the same manner as in Example 11. From 5 ml of each culture, the cells were centrifugally harvested, suspended in 0.5 ml of 100 mM phosphate buffer (pH 6.5) containing 0.05% of (5S)-6-benzoyloxy-5-hydroxy-3-oxohexanoic tert-butyl ester and 8% of glucose, and the reaction was carried out in the same manner. The results are shown in Table 4.

المصدر

DOI: 10.6084/m9.figshare.5104873.v1براءة الاختراع: US07094594B2uspto-grants-2006_08